I don't think I would allow to change water into gasoline, there is to much difference between the two. Maybe with a complex ritual, but nothing on the fly.
Something that I think would be way more in the line with water magic would be having the water emulate the properties of any water based substance. Especially acid, of course.
However, you could possibly declare, that your fire evocation sucks the heat from the water and adds it to the burn damage the fire already does. This would probably result in something like Harry does in Changes.
You have to understand that magic is magic. Evocation and thaumaturgy is the same thing. One is improvised like singing live at a concert while the other is using a recording studio. This analogy is perfect.
You can transmute with evocation sure, but you would do a horrible job at it.
Just look when Listens to Wind fought the Skinwalker. Listens to Wind used evocation to shapeshift, aka transmute himself, which is not against the law because its on self.
About your spoilered part: I believe it was said/written that Listens to Wind has performed a ritual to shapeshift in the past and eventually used it so often it became like the True Shapeshifting power, but of course with an Evocation flavour to it.