... there is no guarantee that she'd be receptive to a so called "Holy Knight."
Michael doesn't often introduce himself as a "Holy Knight," though: he just steps up to help.
And Murphy actually has amazingly-good "people-sense."
It'd make good sense in both Doylist & Watsonian terms.
If Michael is guided to aid her in time of need -- and I allege that (in an Evil!Harry universe) this is likely to happen -- Murphy will take the help, and (cautiously) begin trusting Michael, as he becomes a good source of supernatural intel & an ally in protecting Chicago.