The one I'm most looking forward to is seeing what equivalent upgrades darkside Harry got that lets him take on the Winter Knight in a duel
IIRC there's a WoJ saying that mirror!Harry is closely-allied with Mavra.
Suggests to me that he likely leaned-in on the necromancy.
If I recall correctly the "point of divergence" is supposed to be some event towards the end of Grave Peril.
I'm pretty sure this is correct, yes; specifically, it's a choice Harry makes.
Exactly what choice Harry makes -- the critical divergence -- is, I think, an important issue.
Suppose he takes Bianca's deal -- having "cost" Bianca her playmate, he lets Bianca take the (already half-turned) Susan from him. Immediate consequence -- Susan is a fully-turned Rampire, and Harry's self-image is "I traded-away the woman I loved, to be safe." Note this choice is actually foreshadowed in the book: Jim wrote how hopeless and defeated Harry was feeling.
He didn't expect to win that fight; it was a last-ditch moment of inspiration to summon all the shades of the Rampire victims to get revenge (and a
startlingly powerful act of necromancy, given how untrained / unpracticed Harry was; he's clearly a natural with necromancy!).
I'm sure many of us can project all sorts of futures from that divergence.
On the other hand, let's take the choice at the very end: after all the action's over, Harry tracks Susan to a beach. They talk; she leaves.
Suppose he didn't let her, argued/persuaded/cajoled, "let's just try, for a bit, you can always leave if it's not working," and half-Ramp Susan stayed in Chicago. But, without going down to Latin America, she likely never came to the attention of the Order of St Giles, never got their specialized half-Rampire training, etc. No Maggie Jr, no Red-Court Takedown at Chichen Itza. I bet the Reds won the war against the White Council; maybe (probably) a few WC wizards survived... they likely all hate Dresden's guts for starting the war.
Etc... I think I've seen at least half a dozen different "critical choices" proposed, with more or less convincing arguments.